Formation of vinyl ether derivatives in the reaction of tributyltin hydride with cluster supported Fischer carbene complexes: structural characterisation of [(CO)6Fe2Te2{m-PhC CC(OEt)}W(CO)5]
نویسندگان
چکیده
Treatment of the complex [(CO)6Fe2EE%{m-C(Ph) C–C(OEt) M(CO)5}], (1: E=S, E%=Se; M=Cr; 2: E=S, E%=Se; M=W; 3: E=E%=Te; M=Cr and 4: E=E%=Te; M=W), with excess Bu3SnH in hexane at 0°C produces enol ether derivatives: (CO)6Fe2{m-EC(Ph)(H)-C(E%) C(H)(OEt)} (E/Z-5: E=S, E%=Se and E/Z-6: E=E%=Te). All the compounds have been characterised by IR and H-, Cor Se-NMR spectroscopy. The structure of [(CO)6Fe2Te2{m-(Ph)C CC(OEt)}W(CO)5] has been established crystallographically.
منابع مشابه
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